That represents approximately the same number of active duty troops deployed in Iraq, Syria and Afghanistan.
As of Monday, nearly half of the US has activated guard members to respond to civil unrest.
On top of the District of Columbia, the 23 states that have activated the National Guard are: Arizona, Alaska, California, Colorado, Florida, Georgia, Illinois, Indiana, Kentucky, Michigan, Minnesota, North Carolina, Nevada, Ohio, Pennsylvania, South Carolina, South Dakota, Tennessee, Texas, Utah, Virginia, Washington and Wisconsin.
Additionally, about 45,000 National Guard members are supporting the Covid-19 response
across all 50 states, three territories and D.C., bringing the total number of activated National Guard soldiers and airmen to 66,700.
President Donald Trump said Monday in the Rose Garden that the United States is taking new measures to quell riots across the United States.
"First we are ending the riots and lawlessness that has spread throughout our country," Trump said, adding that he's strongly recommended to governors to deploy the National Guard to "dominate the streets."
Georgia Gov. Brian Kemp, who authorized up to 3,000 National Guard troops on Saturday, tweeted, "These highly trained citizen soldiers will partner (with) law enforcement to preserve peace and protect Georgians in every corner of our great state."
On Sunday, Kemp shared pictures of military vehicles lined up and retweeted photos posted by Georgia National Guardsmen training with shields and batons in their hands.